Photofragmentation and electron detachment of aromatic phosphonate, sulfonate and phosphate oxyanions
نویسندگان
چکیده
The photodetachment energy threshold, as well vibrationally resolved spectral signatures of the lower lying excited states and dipole bound in model aromatic phosphonate, sulfonate phosphate oxyanions, has been investigated using a photofragmentation spectrometer equipped with cold ion trap. effect laser excitation was monitored by mass-selective detection product fragments or, alternatively, measuring yield complementary neutral radicals discriminated according to their kinetic energy. anions phenylphosphate, phenylsulfonate p-toluenesulfonate evidenced expected behavior, characterized predominance ionic fragmentation processes, at low energies, rapidly evolving scenario controlled electron channel higher energies. Surprisingly for such similar system, phenylphosphonate anion does not have any channels only exhibits presence states.
منابع مشابه
Synthesis of new sulfonate and phosphonate derivatives for cation-independent mannose 6-phosphate receptor targeting.
The cation-independent mannose 6-phosphate receptor (CI-M6PR) is essential for the endocytosis of proteins bearing the mannose 6-phosphate (M6P) recognition marker. This study described the synthesis of M6P and M6S analogs presenting greater affinity for CI-M6PR than their natural compounds. Moreover, the finding of their lack of cytotoxicity for human cells and of their increased stability in ...
متن کاملBase and phosphate electron detachment energies of deoxyribonucleotide anions.
Photoelectron spectra of deoxyribonucleotide anions are interpreted with ab initio, electron propagator calculations. Ground-state structures display hydrogen bonds which are not present in less stable minima that resemble Watson-Crick fragment geometries. For the adenosine and thymidine anions, there are two vertical electron detachment energies (VEDEs) within 0.1 eV of each other that corresp...
متن کاملcellular behavior and scanning electron microscope evaluation of pro-root mta, root mta and modified mta on fibroblast l929
چکیده ندارد.
15 صفحه اولpostnatal studies of bats (pipistrellus kuhlii and miniopterus schreibersii) & histomorphology and histochemistry studies of organs and diseases of (neurergus microspilotus and n. kaiseri)
1. to determine whether difference in birth body mass influenced growth performance in pipistrellus kuhlii we studied a total of 12 captive-born neonates. bats were assigned to two body mass groups: light birth body mass (lbw: 0.89 ± 0.05, n=8) and heavy birth body mass (hbw: 1.35 ± 0.08, n=4). heavier body mass at birth was associated with rapid postnatal growth (body mass and forearm length) ...
ذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: European Physical Journal D
سال: 2021
ISSN: ['1434-6060', '1434-6079']
DOI: https://doi.org/10.1140/epjd/s10053-021-00094-8